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71.
Oxa[7]superhelicene: A π‐Extended Helical Chromophore Based on Hexa‐peri‐hexabenzocoronenes 下载免费PDF全文
David Reger Philipp Haines Dr. Frank W. Heinemann Prof. Dr. Dirk M. Guldi Prof. Dr. Norbert Jux 《Angewandte Chemie (International ed. in English)》2018,57(20):5938-5942
A novel π‐extended “superhelicene” based on hexa‐peri‐hexabenzocoronenes (HBCs) has been synthesized by an efficient four‐step synthetic procedure starting from diphenyl ether. Comprehensive structural analysis of the helicene was performed by NMR spectroscopy and mass spectrometry measurements together with X‐ray analysis. Physicochemical analysis of the superhelicene and suitable HBC references revealed it had outstanding fluorescent features with quantum yields of over 80 %. 相似文献
72.
Rahman GM Guldi DM Cagnoli R Mucci A Schenetti L Vaccari L Prato M 《Journal of the American Chemical Society》2005,127(28):10051-10057
A combination of van der Waals and electrostatic interactions was used to integrate SWNT and a suitably functionalized polythiophene into nanostructured ITO electrodes. In the resulting electron donor/acceptor nanocomposites, polythiophene represents the light-harvesting chromophore that readily donates an excited-state electron to the ground-state electron-accepting SWNT. Upon illumination, monochromatic incident photoconversion efficiencies between 1.2 and 9.3% were determined for single and eight-sandwiched layers, respectively. 相似文献
73.
Guldi DM Swartz A Luo C Gómez R Segura JL Martín N 《Journal of the American Chemical Society》2002,124(36):10875-10886
Several generations of phenylenevinylene dendrons, covalently attached to a C(60) core, have been developed as synthetic model systems with hierarchical, fine-tuned architectures. End-capping of these dendritic spacers with dibutylaniline or dodecyloxynaphthalene, as antennas/electron donors, yielded new donor-bridge-acceptor ensembles in which one, two, or four donors are allocated at the peripheral positions of the well-defined dendrons, while the electron accepting fullerene is placed at the focal point of the dendron. On the basis of our cyclic voltammetry experiments, which disclose a single anodic oxidation and several cathodic reduction processes, we rule out significant, long-range couplings between the fullerene core and the end-standing donors in their ground-state configuration. Photophysical investigations, on the other hand, show that upon photoexcitation an efficient and rapid transfer of singlet excited-state energy (6 x 10(10) to 2.5 x 10(12) s(-1)) controls the reactivity of the initially excited antenna portion. Spectroscopic and kinetic evidence suggests that yet a second contribution, that is, an intramolecular electron-transfer, exists, affording C(60)(.-) -dendron(.+) with quantum yields (Phi) as high as 0.76 and lifetimes (tau) that are on the order of hundreds of nanoseconds (220-725 ns). Variation of the energy gap modulates the interplay of these two pathways (i.e., competition or sequence between energy and electron transfer). 相似文献
74.
Guldi DM Gonzalez S Martin N Anton A Garin J Orduna J 《The Journal of organic chemistry》2000,65(7):1978-1983
Triazoline[4,5][60]fullerenes are strong electron acceptors that form with tetrathiafulvalene (TTF), a novel type of donor-acceptor dyad exhibiting efficient improved electron-transfer dynamics. In particular, a rapid photoinduced intramolecular electron transfer, forming a charge-separated state, is followed by a slow charge recombination to generate the fullerene triplet excited state in moderate quantum yields. 相似文献
75.
Guldi DM 《Chemical Society reviews》2002,31(1):22-36
Fullerenes and porphyrins are molecular architectures ideally suited for devising integrated, multicomponent model systems to transmit and process solar energy. Implementation of C60 as a 3-dimensional electron acceptor holds great expectations on account of their small reorganization energy in electron transfer reactions and has exerted a noteworthy impact on the improvement of light-induced charge-separation. This article describes how the specific compositions of porphyrin chromophores linked to C60--yielding artificial light harvesting antenna and reaction center mimics--have been elegantly utilized to tune the electronic couplings between donor and acceptor sites and the total reorganization energy. Specifically, the effects that these parameters have on the rate, yield and lifetime of the energetic charge-separated states are considered. 相似文献
76.
Guldi DM Giacalone F de la Torre G Segura JL Martín N 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(24):7199-7210
Two triads (donor-spacer-acceptor), exTTF-BN-C60 (6) and ZnP-BN-C60 (7), in which electron donors (i.e., exTTF or ZnP) are covalently linked to C60 through a chiral binaphthyl bridge (BN), have been prepared in a multistep synthetic procedure starting from a highly soluble enantiomerically pure binaphthyl building block (1). Unlike other oligomeric bridges, with binaphthyl bridges, the conjugation between the donor and the acceptor units is broken and geometric conformational changes are facilitated. Consequently, distances and electronic interactions between the donor and C60 are drastically changed. Both donor-spacer-acceptor (D-s-A) systems (i.e., 6 and 7) exhibit redox processes that correspond to all three constituent electroactive units, namely, donor, BN, and C60. Appreciable differences were, however, observed when comparing triad 6, in which no significant exTTF-C60 interactions were noted, with D-s-A 7, whose geometry favors donor-acceptor and pi-pi interactions that result in ZnP-C60 electronic communication. This through-space interaction is, for example, reflected in the redox potentials. Excited-state studies, carried out by fluorescence and transient absorption spectroscopy, also support through-space rather than through-bond interactions. Although both triads form the corresponding radical-ion pair, that is, exTTF*+-BN-C60*- and ZnP*+-BN-C60*-, dramatic differences were found in their lifetimes: 165 micros and 730 ns, respectively. 相似文献
77.
78.
Even M Heinrich B Guillon D Guldi DM Prato M Deschenaux R 《Chemistry (Weinheim an der Bergstrasse, Germany)》2001,7(12):2595-2604
Grafting of a ferrocene-containing liquid-crystalline malonate derivative to C60 led to the mixed fullerene-ferrocene material 1 which gave rise to a smectic A phase. Cholesterol was used as liquid-crystalline promoter. X-ray diffraction experiments and volumetric measurements indicated that 1 is organized in double layered structures. The corresponding supramolecular organization within the mesomorphic lamellar phase is characterized by a microsegregation of the different units (ferrocene, fullerene, and cholesterol) in distinct sublayers. In such a smectic A phase, C60 imposes the arrangement of the other molecular moieties. Photophysical studies revealed that electron transfer occurs from the donor ferrocene to the electron accepting fullerene. The formation of a long-lived radical pair, with lifetimes of the order of several hundred nanoseconds, was confirmed by time-resolved spectrometry, especially in the near infrared region, in which the radical anion of the fullerene moiety displays its characteristic fingerprint absorption. 相似文献
79.
Dr. Luis M. Mateo Luca Sagresti Dr. Yusen Luo Prof. Dirk M. Guldi Prof. Tomas Torres Dr. Giuseppe Brancato Dr. Giovanni Bottari 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(64):16049-16055
Tetracyanobuta-1,3-diene (TCBD) is a powerful and versatile electron-acceptor moiety widely used for the preparation of electroactive conjugates. While many reports addressing its electron-accepting capability have appeared in the literature, significantly scarcer are those dealing with its chemical modification, a relevant topic which allows to broaden the chemical space of this interesting functional unit. Here, we report on the first example of a high-yielding cyano-Diels-Alder (CDA) reaction between TCBD, that is, where a nitrile group acts as a dienophile, and an anthryl moiety, that is, acting as a diene. The resulting anthryl-fused-TCBD derivative, which structure was unambiguously identified by X-ray diffraction, shows high thermal stability, remarkable electron-accepting capability, and interesting electronic ground- and excited-state features, as characterized by a thorough theoretical, electrochemical, and photophysical investigation. Moreover, a detailed kinetic analysis of the intramolecular CDA reaction transforming the anthryl-TCBD-based reactant into the anthryl-fused-TCBD product was carried out at different temperatures. 相似文献